Properties of Solids and Liquids: Physics | JEE Main
Under isothermal condition, the pressure of a gas is given by P=aV−3, where a is a constant and V is the volume of the gas. The bulk modulus at constant temperature is equal to
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Step-by-step solutionView
Correct answer
Using the definition of bulk modulus B=−VdVdP on P=aV−3, we find B=−V(−3aV−4)=3aV−3=3P.
Option analysis
Why each option works or fails
A · 2P
Believing that the bulk modulus is divided by the power or index rather than multiplied by it. Differentiate P=aV−3 with respect to V to get dVdP=−3aV−4, then multiply by −V to obtain 3P.
B · 3 P
This is the correct answer. Evaluating B=−VdVdP=−V(−3aV−4)=3(aV−3)=3P directly gives 3P.
C · 2 P
Incorrectly applying the power rule as decreasing the magnitude of the exponent from 3 to 2. The derivative of V−3 brings down a factor of −3, giving a multiplier of 3 after accounting for the negative sign in the bulk modulus formula.
D · P
Assuming the isothermal bulk modulus of any gas is always equal to P, which is only true for an ideal gas where PV=constant. Use the given equation of state P=aV−3 (PV3=a) rather than the standard ideal gas relation PV=constant.
Reviewed route
Solution
StepWorking
01given
Pressure-volume relation: P=aV−3 where a is a constant.
02find
The bulk modulus B of the gas at constant temperature.
03strategise
Bulk modulus is defined as B=−VdVdP. Differentiate P=aV−3 with respect to V and substitute into the definition.
04execute
Differentiating P with respect to V gives dVdP=−3aV−4=−3VP. Then, B=−V(−3VP)=3P.
✓verify
For a polytropic process PVn=const, the bulk modulus is nP. Here n=3, so B=3P, which is positive and physically consistent.
Why is there a negative sign in the bulk modulus definition?
Because an increase in pressure produces a decrease in volume, so dV/dP is negative. The negative sign ensures that the bulk modulus is a positive physical quantity.